Energy storage capacity of aluminium Aluminium has a high storage density. Theoretically, 8.7 kWh of heat and electricity can be produced from 1 kg of Al, which is in the range of heating oil, and on a volumetric base (23.5 MWh/m 3) even surpasses the energy density of heating oil by a factor of two. 4.2. The Power-to-Al process
Although it is possible that first systems for seasonal energy storage with aluminium may run as early as 2022, a large scale application is more likely from the year 2030 onward.
Dudita M, Farchado M, Englert A, Carbonell D, Haller M. Heat and power storage using aluminium for low and zero energy buildings. In: Proceedings CLIMA 2019 -13th REHVA World Congress, Bucharest, Romania: 2019, p. 1–6, accepted for publication. US DOE. Fuel Cell Technologies Market Report 2015. 2016.
Aluminium redox cycles are promising candidates for seasonal energy storage. Energy that is stored chemically in Al may reach 23.5 MWh/m 3. Power-to-Al can be used for storing solar or other renewable energy in aluminium. Hydrogen and heat can be produced at low temperatures from aluminium and water.
Aluminium can be used to produce hydrogen and heat in reactions that yield 0.11 kg H 2 and, depending on the reaction, 4.2–4.3 kWh of heat per kg Al. Thus, the volumetric energy density of Al (23.5 MWh/m 3) 1 outperforms the energy density of hydrogen or hydrocarbons, including heating oil, by a factor of two (Fig. 3).
With the assumptions of Table 4 this leads to a demand of 2662 kg of aluminium (443 kg per apartment). The PV field covers 34% of the electricity demand directly or via the local battery, and only 1% is purchased from the grid. The electricity flows of the system are shown on the left plot of Fig. 8.
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Aluminum redox batteries represent a distinct category of energy storage systems relying on redox (reduction-oxidation) reactions to store and release electrical energy. Their distinguishing feature lies in the fact that these redox reactions take place directly within the electrolyte solution, encompassing the entire electrochemical cell.
The overall volumetric energy density, including the thermal energy from Equation 1 and the oxidation of the resulting hydrogen (e.g., reacted or burned with oxygen), amounts to …
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A new concept for seasonal energy storage (both heat and power) for low and zero energy buildings based on an aluminium redox cycle (Al→Al3+→Al) is proposed. The main advantage of this seasonal energy storage concept is the high volumetric energy density of aluminium (21 MWh/m3), which exceeds common storage materials like coal.
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