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Normally, as the lead–acid batteries discharge, lead sulfate crystals are formed on the plates. Then during charging, a reversed electrochemical reaction takes place to decompose lead sulfate back to lead on the negative electrode and lead oxide on the positive electrode.
The discharge state is more stable for lead–acid batteries because lead, on the negative electrode, and lead dioxide on the positive are unstable in sulfuric acid. Therefore, the chemical (not electrochemical) decomposition of lead and lead dioxide in sulfuric acid will proceed even without a load between the electrodes.
Figure 4 : Chemical Action During Discharge When a lead-acid battery is discharged, the electrolyte divides into H 2 and SO 4 combine with some of the oxygen that is formed on the positive plate to produce water (H 2 O), and thereby reduces the amount of acid in the electrolyte.
The Charging begins when the Charger is connected at the positive and negative terminal. the lead-acid battery converts the lead sulfate (PbSO 4) at the negative electrode to lead (Pb) and At the positive terminal, the reaction converts the lead sulfate (PbSO 4) to lead oxide. The chemical reactions revers from discharging process
The Discharge of the lead-acid battery causes the formation of lead sulfate (PbSO 4) crystals at both the positive electrode (cathode) and the negative electrode (anode), and release electrons due to the change in valence charge of the lead. This formation of lead sulfate uses sulfate from sulfuric acid which is an electrolyte in the battery.
The lead-acid battery has a nominal voltage of about 2v, it can vary from 1.8v at loaded at full discharge to 2.40v in an open circuit at full charge. The calculation of charging voltage can be done with voltage 2.40v/cell. 12v lead acid battery can be made from 6 cells connected in series.
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